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Surfactants in Shampoo Bars

In the quest for healthier and more environmentally friendly hair care products, the choice between natural surfactants and synthetic surfactants like Sodium Lauryl Sulfate (SLS) has become a significant consideration. Understanding the differences between these surfactants can help soap makers and consumers make informed choices that align with their personal values and hair care needs.

three tan and beige shampoo bars

What Are Surfactants in Shampoo Bars

Surfactants are compounds that help cleanse the hair and scalp by breaking down oils and dirt accumulated in our hair, allowing them to be washed away with water. They are a crucial component of hand-crafted shampoo bars and soaps, providing the lathering and cleansing action we associate with hair washing.

By understanding the differences between natural and synthetic surfactants, you can choose to create shampoo bars that meet your hair care needs while aligning with your values regarding natural ingredients and environmental impact.


Natural Surfactants

Natural surfactants are derived from plant-based sources, such as coconut oil, palm kernel oil, or olive oil. These surfactants are considered milder and often preferred for their gentler impact on the hair and scalp.

a coconut cut into two with three creamy white shampoo bars

Synthetic Surfactants

Synthetic surfactants are man-made and often used in conventional shampoos for their strong cleansing abilities and cost-effectiveness. There are many small business artisan soap makers who also use them in the creation of their products.

Here are some examples of both natural and synthetic surfactants:


Natural Surfactants

Natural surfactants are derived from plant-based sources and are often favoured for their gentle cleansing action and environmental benefits.

  • Cocamidopropyl Betaine: Derived from coconut oil, this mild surfactant is known for its ability to create a rich lather without being harsh on the skin or hair. It is commonly used in natural and organic personal care products.

  • Decyl Glucoside: Made from glucose derived from corn starch and fatty alcohols from coconut oil, decyl glucoside is a gentle, biodegradable surfactant suitable for sensitive skin. It is often found in eco-friendly and natural shampoos.

  • Lauryl Glucoside: Another sugar-based surfactant, lauryl glucoside is made from coconut or palm kernel oil. It is non-irritating and biodegradable, making it a popular choice in natural and organic formulations.

  • Sodium Coco-Sulfate: Although similar in name to synthetic surfactants, sodium coco-sulfate is derived from coconut oil. It provides effective cleansing while being milder than its synthetic counterparts.

    a man washing his hair with a shampoo bar

Benefits of Natural Surfactants

Gentle Cleansing: Natural surfactants are less likely to strip the hair and scalp of their natural oils, preserving the hair's moisture balance and reducing the risk of dryness or irritation.

Biodegradable and Eco-Friendly: Plant-based surfactants are typically biodegradable, making them a more environmentally friendly choice. They break down more easily in nature, reducing their impact on aquatic ecosystems.

Suitable for Sensitive Scalps: Their mild nature makes natural oil surfactants an excellent choice for individuals with sensitive skin or conditions like eczema and psoriasis, as they minimize the risk of irritation.

Nourishing Properties: Many natural surfactants retain beneficial nutrients from their source oils, which can contribute to healthier and more nourished hair.


Synthetic Surfactants

  • Sodium Lauryl Sulfate (SLS): A common synthetic surfactant known for its powerful cleansing and foaming properties. While effective, it can be harsh on the hair and scalp.

  • Sodium Laureth Sulfate (SLES): A milder derivative of SLS, SLES is designed to be less irritating while still providing a rich lather. It is widely used in commercial shampoos.

  • Ammonium Lauryl Sulfate: Similar to SLS, this surfactant is used for its strong cleansing action. It is often found in cheaper, mass-market shampoos.

  • Cocamide DEA: A synthetic surfactant derived from coconut oil and diethanolamine. It is used to enhance the lathering properties of shampoos, although it has faced scrutiny over potential health concerns.


Highlighting Sodium Lauryl Sulfate (SLS)

SLS is a synthetic surfactant commonly used in shampoos (even hand-crafted shampoo bars!) foaming bath salts and bombs and other commercial cleaning products. Known for its strong cleansing power and ability to produce a rich lather, SLS is a cost-effective ingredient favoured by many commercial hair care brands. Unfortunately, it is also widely used by artisan soap makers in some of the products listed above.


Any time SLS or other fine powders are used, safety precautions always need to be applied.

a woman wearing a rebreather safety mask with powder particles floating upwards towards her face

Drawbacks of SLS Surfactant

Harsh on Hair and Scalp: SLS can be overly aggressive, stripping away natural oils and potentially leading to dryness, irritation, or an imbalance in scalp oil production.

Environmental Concerns: SLS is less biodegradable than natural surfactants, posing a greater risk to aquatic life and contributing to environmental pollution.

Allergic Reactions: Some individuals may experience allergic reactions or sensitivities to SLS, manifesting as redness, itching, or flakiness on the scalp.

Potential Long-Term Effects: Frequent use of SLS-containing products can lead to cumulative effects, such as increased hair breakage or a compromised scalp barrier.


Making the Right Choice

Choosing between natural surfactants and synthetic surfactants like SLS depends on individual preferences and priorities. Those who prioritize a gentler, more natural approach to hair care may opt for products containing natural surfactants, appreciating their mildness and environmental benefits. Conversely, individuals seeking strong cleansing power without particular sensitivities might still consider products with SLS.


Ultimately, the decision involves weighing the benefits of natural ingredients against the practicality and effectiveness offered by synthetic surfactants. By understanding these differences, soap and shampoo creators and consumers can select shampoo bars that best suit their hair care needs and support their commitment to a sustainable and healthy lifestyle.


Let me know what your experience has been or leave a comment below.

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